Green house gases, renewable energy schemes and sustainability

(Project member SATRAPS- University  Technology  Malaysia-UTM, Malaysia)

Introduction

The use of energy has been identified with the dawn of human civilization. At the beginning of human civilization , people used to draw their energy mostly from the exploitation  of human and  animal forces . Wood from forests were also another resource used for cooking and heating –though wind and water energy  had also limited site specific use .In fact ,  till around a century and quarter  back,  vegetable oils /fats were  the most popular  and virtually the only resource for lighting purposes , throughout  the globe with electricity an unknown commodity .

With the passage of time fossil fuels were discovered. Its use remarkably increased only after the industrial revolution in the 18th century—though coal was a not an unknown fuel in China since earliest times . The landmark discovery of steam engine in  1712  paved the way with accelerated growth of economy along with  the faster use of  fossil fuels  The abundant resource of coal with much higher calorific value prompted the replacement of wood as a source of  fuel. Advancement of economy started growing hand in hand with the availability and consumption of fossil fuel.

With the economy growing up , the standard of living improved ushering in the growth of industries like  transport,   mining, construction and chemicals coming  up–opening up still further scope of use of fossil fuels  With it  the transition started shifting the world economy from the  agricultural base to focussing  on the lucrative  growth of faster industrialisation on all fronts .The  invention of electricity by the end  of 19th century completely  changed the dimension of mankind offering a  much better quality of life .A new era started with power sectors coming up and thereby  facilitating  the  economic growth  of the nations  Thus the hall mark of industrial nations with economic advancements has now been  identified with the generation of electricity . As a result of this , the demand for consumption of fossil fuels  grew with leaps and bounds,  within the last 100  years we have consumed more fuel than that used since the last  few millennium.

The big leap forward on fossil fuel consumption rate globally , began from the scope of availability of electricity harnessing the fossil fuels .It is of interest to note  that the generation of electricity , first used in 1883 , was rather a costly process then -making it costlier than the equivalent heat energy  available from these fossil fuels –coal/oil/gas .But the advantages gained from its wide scale services made  it a key player in  all sorts of technological advancements and thereby decisive  in improving upon the economy of a country.

 Of course  there have been marked disparity in quantum of energy use and thereby of the degree of economic development between OECD (Organization of economic co-operation and development)  and Non-OECD countries for obvious reasons . The former included developed countries like, USA , Canada , most European countries , Australia and lately Japan , plus some Latin American countries etc ; whence non-OECD countries are mainly the Asian countries excluding Japan , African  and some Latin American countries.

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 There is a close relationship between the  usage of energy   with  general level of economic activity. Also,  the wide scope of use of fossil fuels (use of oil as transport fuel & in petrochemical productions in addition to power production, use of  coal in metallurgical processes besides power generation etc)  make their  impact on local economy so deep , that for every price rise of fuel  its impact is felt on the overall economy of the country causing  increase in  inflation.  Because of these   economic promises, the rather poorer non-OECD countries have  projected a rather faster growth rate of energy use than that of the  already developed OECD countries  –whose present energy consumption rates are already many times higher than the non-OECD countries.  

But  such  ever increasing faster usage rate of fossil fuels,  to achieve   economic progress , posed  too big a burden for nature to cope up with. We are thus now confronted with  the resource crunch of the energy rich fossil fuels  threatening the sustained development.

In addition to it,  the  environmental issues like global warming, ozone hole and such eventualities from higher emission rate of green house gases has invited the attention of energy planners and policy makers –which is a much talked of topic now 

Green House Gases and Global warming  

 The earth absorbs nearly 70% of the incoming solar radiation and then tries to cool down   emitting  long wavelength infrared radiation . This radiation is absorbed by some atmospheric gases , termed green house gases ; and the effect of temperature rise caused thereby  trapping the escaping heat,  is called the green house effect.   The term is coined from the known practice of the  gardeners  growing  vegetables in green house structures of glass/plastic canopy to  trap the  heat of the incident sunlight .

 This phenomenon , first  investigated by S. Arrhenius in 1896, showed that the green house gases emit also long infrared radiation up above the space and down below the earth. The warming of atmosphere is caused from the latter and the gases responsible for heating are : Water vapour , Carbon Dioxide, Argon, Neon, Helium, Methane, Hydrogen, Nitrous Oxide and Ozone.. Besides these atmospheric green house gases , there are other man-made green house gases as well , like the three groups of fluorinated compounds – Sulfur hexafluoride , HFCs and PFCs . But Oxygen and Nitrogen , the major atmospheric constituents , have no green house effect as  they  neither absorb nor emit infra-red radiation . This is because  of the fact that they are  homo nuclear diatomic molecules with no net change in dipole moment when they vibrate .

The role of water vapour in atmospheric heating is quite interesting . Water vapor [not cloud which rather restricts sun’s rays reflecting it back ] have rather synergistic effect in green house heating.  Rise in temperature from green house effect results in increase in water vapor content , with further temperature rise in the troposphere, which is  the atmospheric zone that we live in. This causes  more  evaporation of ocean water aggravating further  temperature rise and the feedback cycle continues till the  equilibrium is reached  But the atmospheric heating from water vapour have only local and temporary effect  with its fluctuating concentration in the atmosphere .

In fact , the three factors that influences the degree of  warming from  green house gases are – the global warming potential (GWP) of the particular gas, its concentration in the atmosphere and the  mean life. CO2 (carbon-di-oxide) , that originates from burning of fossil fuels  has GWP ‘1’,  with lifetime of several hundred years ; but can increase to several thousand years in case of their  large input in the atmosphere.  CH4(methane),  that may originate both from fossil fuel burning as well as degeneration from anaerobic bacteria over rice fields/wastes , has GWP ‘23’ over 100 years lifetime and just ‘7’ for over 500 years lifetime –because of its atmospheric degradation to water and CO2  over longer periods. Nitrous oxide originating from both fossil fuel burning /fertiliser plants etc type  chemical industries , have a GWP ‘296’ with around 100 years lifetime. Man made CFCs and  fluorinated compounds , made for  refrigerants etc , have GWP several thousand with around 14 years life time.

However,  contribution towards warming in case of other green house gases are negligible compared to CO2, despite their higher GWP values;  because  their  atmospheric concentration is negligible . But it is also to be noted that,  in an  eventuality of desorption  of clathrated methane from  ocean bed/rocks etc or,  the release of frozen methane from  polar zone , it may play a havoc in global warming – in the eventuality of  the release of methane from such sources in very large quantities.

It may be  relevant to add   that – but for the green house gases with no scope for  retention of heat , we would have frozen during night time.  The much-talked of global warming  arises because of the unabated increment in  concentration of green house gases , particularly  CO2  – from large scale use of fossil fuels, resulting in the enhanced green house effect , which is in fact of global concern now,

If the CO2  concentration  exceeds 450 PPM from the present 350  PPM level – then there may be irreversible temperature rise continuing  for centuries. Sea level may rise by 5-12 m , drowning many low lying areas in the globe –from melting of snow in the ice cap of Greenland and Western Arctic region.  On the one hand the  draught affected areas may increase  with  simultaneous rise in the frequency of flood risk—due to the changes  in rainfall pattern globally

Ozone Hole – In addition to the global warming from green house gases  (CO2 mainly) we are confronted with another problem, termed ozone hole –which has already done some damage towards maintaining environmental equilibrium. Ozone (O3 ), the allotrope of Oxygen (O2 ),  acts as a shield  in the Stratosphere ( above the Troposphere that we live in ) – by interacting with, and thereby reducing the harmful ultraviolet rays of the  sunlight reaching us. Ozone hole is the dent caused in the above ozone layer, from the chemical reaction of CFCs and such halides –breaking down the ozone molecules to Oxygen.

Ozone depletion as such is not directly linked to global warming , other than inviting health hazard from incoming ultraviolet rays of the sun .But the halides like , CFCs etc,  responsible for  breaking down the  ozone  layer, are themselves very  potent in their green house effect as well . Hence , the  production CFCs was  restricted through an international treaty ,the Montreal agreement made in 1989 .

As a result of this treaty,  steady decline has of course been observed  in the production of CFCs and such harmful halides –that threatened Ozone hole formation ( besides global warming ). But the damage already done in depletion of ozone layer in Antarctic and such place ,  would take decades to get recovered.

Fossil fuel  Resource Crunch .

The large scale usage of fossil fuel  is inviting disastrous environmental consequences of global warming ,ozone hole etc problems. In addition to the above , the increasing  trend of their use  like , oil./gas /coal etc   for achieving fast economic growth , we risk rapid depletion and exhaustion of these very fuels.    It is only a question of time that these concentrated cheap fuel sources , that took  million of years to be formed from biological and geological processes , run the risk of getting totally depleted ,sooner or later 

It has been apprehended   that the planet may get depleted from oil by next half a century , with the current rate of consumption.  Coal may last a little longer, another  century or so.  In fact  the production of fixed resources would follow the law of diminishing return – a sharp decline following the  peak production. In fact on reaching the peak production a stage is reached when the energy required for production –like , manufacturing drilling rigs , process of exploring new oil field, and the various stages of production to lift the oil to surface –may far exceed the amount of energy as may be availed  and also  becomes  economically non-viable

The ratio of reserve/production ,i.. e.   the R/P ratio of fossil fuels in the global perspective with the present rated use has been predicted to be :– Oil – 40 years hence ; Natural gas -60 years; whence Coal may last a little longer – another 200 years. However ,  there remain  uneven distribution of these resources , in the global perspective .

Sustainable Development .

It has been shown in previous sections how the immediate  gains of  economic improvements,  from the increasing trend of fossil fuel exploitation, threatens our future.  If the current trend of fossil fuel use continues ,we run the risk of meeting environmental disasters in addition to facing a retrograde movement of civilization with no electricity or power availability situation – having  no fuel left  for harnessing it . That is why scientists and planners started thinking ahead in terms of sustainable  development . It means a developmental strategy that would be able to meet the needs of the present without compromising the ability of the future generation to meet their own needs.—both towards energy and raw materials .

It may be relevant  to point out here , that the important policy decisions adopted by world bodies on sustainable development,  does not confine in the energy issues only.  It also ensures arresting species extinction ( plants and animals) , addressing to the environmental issues affecting  soil /land/water, in addition to the gradual extinction of mineral and other resources including energy  resources. The guiding principles underlying the sustainable development thus states  categorically that :

•           “Each generation should   require the diversity of resource base so that it does not unduly restrict the options  available to future generations.

•           Each generation should maintain the planets overall qualities so that it does not get into worse condition than received.

•           Members of every generation should have comparable rights of access to the legacy of past generation and should conserve this access to the future generations”

As Energy is the key player in all developmental work,  Sustainable Development Commission in their 9th session in 2001,  took a definite stand for adoption of  alternate resources of energy  which  gets automatically replenished on consumption, termed as Renewable Energy, like sunlight, wind, hydropower etc. They are clean energy virtually free from generating green house gases and their large scale uses not only decrease the present increasing trend of green house gases , but assures steady and virtually unlimited supply of energy – from diverse sources ,  as suited to the site concerned .

Renewable Energy .

 Resources of Renewable Energy could be from varied fields .Some of the important ones are:

•           Tapping the energy of solar insolation over the earth’s surface –called the solar energy.

•           Generating oils or , gases from decomposition /degeneration of bio sources , including bio-wastes  – called bio-fuels.

•           Tapping the hydro-power , either natural or creating artificial level difference of natural water bodies and/or the energy  of the flow of water bodies. 

•           Wind energy of blowing wind.

•           Tidal current , and 

•           The huge untapped reservoir of energy in Oceans –termed Ocean energy

But till date,  only a small percentage of these  are  being tapped,  compared with the conventional fossil fuels.  Exhaustive R& D studies are hence undertaken in different  countries  to make  such energy resources  technically viable and economically affordable  in the long run.

A brief account of some of these RE schemes are enumerated below.

Solar Energy–  Direct tapping of solar radiation can  be  done,  either by the generation of electricity from   photovoltaic effect of incident solar radiation using solar cells (Photo -Voltaic -PV) ,or, utilizing the heating effect of the solar insolation.  Solar cells (PV),  mostly silicon based, are  semiconductor materials, which  conduct electricity   when  light falls upon them.   It requires an array of batteries and inverters for storing the generated electricity, which can  to be made available in the absence of sunlight (night time), and also for converting DC to AC power.  These are particularly useful in inaccessible places.

Wind Energy (both off-shore & on-shore wind farms) -It involves around $1 million capital outlay per megawatt (MW) power generation, even for a good cut in wind speed (3 -5m/s, but not exceeding 15m/s). The scope of availability of wind resource with optimum wind speed -for both on shore and off-shore  is  however limited; though the latter has  higher resource potential. Power production cost of wind energy are however, competitive with power generation cost from fossil fuel resources.

Bio-Fuels – They are availed at the cost of agricultural land use and with the requirement of abundant water supply for the growth of agricultural feedstock (biomass -which are plants or plant wastes consisting of cellulose, hemicellulose or lignin type carbon-based compounds); they being the primary resource for availing such energy type12. Of course, they have an advantage of their scope for use as transport fuel.

Ocean energy schemes- Amongst the three ocean energy schemes, wave energy, Ocean thermal energy conversion system  (OTEC) and tidal energy, it is the tidal energy   technology which is rather more matured from application point of view, though suitable exploitable sites of it are limited globally.  La rance Barrage in France is producing 240MW power since 1969. Though it is available only 10hours a day, its power generation can  however be properly programmed, being predictable. 

However OTEC   has immense potential of emerging as the viable technology in its 2nd/3rd generation schemes, mainly because of its scope of availability of huge  by products providing not only commercially viable energy production but also providing food security and potable water.   

Ocean Thermal Energy conversion (OTEC)  system  

Ocean  receives huge  radiant energy from the Sun which heats up the ocean surface water.The  surface temperature profile of the ocean graduallly decreases with depth from the exponential decrease of light energy following  Lambert’s law, making the  bottom layer cooler, with further  cooling caused from  the flow of heavier bootom polar water at 4oC.  Thus a  temperature differential is caused in the ocean between  the warm surface layer water and  cooler bottom layer water. This  opens  up  the scope of generating power using  thermodyanamic cycle. Power generation from such method  is termed as  ocean thermal energy conversion (OTEC) system. Because of the high specific heat of water, the surface temperature of the ocean is mostly retained during  night as well,   assuring round the clock supply of power  from OTEC. It  has been estimated that heat energy available  from 60 million sq. km. of tropical seas  could be  equivalent to 250 billion barrels of oil.

It is thought that power produced from OTEC if converted to the production of hydrogen (by splitting water from electrolysis) it would save cable cost of power transmission, since hydrogen fuel cell combine can produce electricity. Besides it offers a method on storage of electricity without the need for battery.  

Hydrogen-  It can be availed  by splitting of water and also leaves behind nothing but water on its liberation of the energy, hence it has been identified to be the future energy source in the new millennium.

Thus hydrogen, the future energy source,  ensures not only the energy supply & security, but also climate stewardship with ensured sustainability, with particular inclusion of transport sector providing mobile fuel.

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